منابع مشابه
(4-Chlorobenzohydrazidato-κ2 N′,O)[2-(4-chlorobenzoylhydrazono-κ2 N,O)propionato(2−)-κO]oxidovanadium(V)
In the crystal structure of the title compound, [VO(C(7)H(6)ClN(2)O)(C(10)H(7)ClN(2)O(3))], the V(V) atom is N,O-chelated by the chloro-benzoyl-hydrazidate anion and O,N,O'-chelated by the (chloro-benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds i...
متن کاملLEWIS-BASE ADDUCTS OF LEAD(II) COMPOUNDS V,* SYNTHESIS AND STRUCTmAL CHARACTEREATION OF MONONUCLEAR (ACETATO-0,O') BIS(2,Zr-BIPYRIDINE) (PERCHLORATO-0,O') LEAD(II) AND BIS (2,Z'-BIPYRIDIW) BIS(PERCHL0RATO-0,O') LEAD(II)
The synthesis and single-crystal X-ray structure determination of the title compound [(bipy) , Pb(0 ,CMe) (O ClO )] (1) and [(bipy) Pb(ClO ) ] (2) is described. Compound (I) crystallizes in the triclinic space group P1(2), a= 7.384(2), b= 12.824(3), c= 10.622(6) A, ?= 73.41(2), ?= 80.98(2), ?= 73.68(2)', Z= 2, and R =0.033 for 3408 independent reflections .Compound (2) crystallizes in the ...
متن کاملCrystal structure of (2-formylphenolato-κ2 O,O′)oxido(2-{[(2-oxidoethyl)imino]methyl}phenolato-κ3 O,N,O′)vanadium(V)
In the unsymmetrical title vanadyl complex, [V(C9H9NO2)(C7H5O2)O], one of the ligands (2-formyl-phenol) is disordered over two sets of sites, with an occupancy ratio of 0.55 (2):0.45 (2). The metal atom is hexa-coordinated, with a distorted octa-hedral geometry. The vanadyl O atom (which subtends the shortest V-O bond) occupies one of the apical positions and the remaining axial bond (the longe...
متن کاملThe structure of epitaxial V 2 O 3 films and
Medium energy ion scattering (MEIS), using 100 keV H incident ions, has been used to investigate the growth of epitaxial films, up to thicknesses of ~200 Å, of V2O3 on both Pd(111) and Au(111). Scattered-ion energy spectra provide a measure of the average film thickness and the variations in this thickness, and show that, with suitable annealing, the crystalline quality is good. Plots of the sc...
متن کاملThe V 2 O 3 ( 0001 ) surface termination : phase equilibrium
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ژورنال
عنوان ژورنال: Circulation
سال: 2000
ISSN: 0009-7322,1524-4539
DOI: 10.1161/01.cir.101.10.1080